The optimisation of the simulation of diffusional transport to a microsphere electrode and its application to electrogenerated chemiluminescence

Abstract

The application is reported of the three layer finite implicit (3LFI) method for the simulation of electrogenerated chemiluminescence at a microsphere electrode. Two different transformed coordinates in the radial coordinate were employed, a conformal map and an exponentially expanding grid, with aim of optimising the modelling of the diffusion under non steady state conditions.